I don't use darktable, but a compelling reason to use it is that it can guarantee a scene-referred workflow; you can actually inspect the order of operations to confirm that. I don't think you can confirm that with any of the commercial softwares.
I have no idea if any commercial software can do this, nor why it would be useful?
I just skimmed the thread, may already have been defined, but 'scene-referred' means the all the operations to color are done before the tone curve lifts the image data from the original linear magnitudes of the capture.
Why is this needed?
It means that you do not need to worry about over-exposing until the very last step.
In Lightroom (and others), only three sliders can retrieve color from white: Exposure, Highlights, Whites. Any other slider, such as the tone curve or levels, or clarity, or contrast, can turn white to grey, but the color is lost.
Not so in darktable (or video editors, or video game color grading, which all use scene-referred editing pipelines). Over there, any old slider can modify brightness in any old way without losing data.
This has consequences: since only those three sliders can rescue highlights color, that's what you must use them for. This often means you have to do counter-intuitive things, like lower highlights until the color looks right, but that darkened your midtones, so now you must raise shadows to compensate. But now you've got a flat image, and must compensate that with contrast. As another example, the Exposure slider almost always needs compensation with highlights and is pretty useless on its own. You get used to this, and it works well, but it is a strange dance if you step back and think about it.
Once you get used to the way darktable works, this kind of inter-dependent editing logic looks silly and inefficient. Darktable uses exposure to expose, without needing to worry about your highlights.
Another aspect is that scene-referred color does not conflate contrast with saturation. In Lightroom, the contrast slider and the tone curve also add saturation. That's a consequence of color information being lost in highlights and shadows, which makes tonal and color adjustments interlinked. Of course everything is built with this in mind and compensates accordingly, and you get used to it.
But in darktable you just don't need to think about it. Contrast changes contrast, not saturation. Tonal adjustments leave color alone. Again, once you get used to this kind of editing, it makes things simpler, and the alternative starts looking silly.
I've used Lightroom and Capture One for several years. But at the end of the day, I prefer editing in darktable. Since operations are more independent, I find them easier to reason about. And I just like this analytical mode of editing.
However, let me very clearly state that this is
purely a matter of preference. When I look back at my photos, I can't tell whether they were edited with Lightroom or Capture One or Darktable. They all do their job, so long as you're proficient with them. Your own skill is much more important than the tools you use.