I am curious why you don't want to use the shutter button. Digital film is pretty inexpensive.
Thanks for the replies!
3 main reasons why I don't want (or can't) sync with the shutter in the main camera:
1. The main camera is shooting all over the field (in this case football/soccer) and not just in the goal area. Having them synced at all times leaves me with thousands of useless images that I would simply prefer not having to deal with (even though there are efficient methods).
2. The hotshoe only triggers when I am in mechanical (or EFCS) and not in electronic shutter mode, leading to a need to trigger the remote in some other way if I am using the latter.
3. The memory card on the remote fills up quickly and I don't have access to replacing it during a game (and no appetite to spend money on huge expensive memory cards just for this).
I halve also seen solutions using a foot pedal to trigger the PocketWizard, but I am often sitting on the ground with my legs stretched out so it is not straight-forward to push it. Hence, the need for something I can operate with my hands.