Would you be interested in looking at what happens with a spectral training set? There is an issue with a spectral training set in that the intensity at the short and long wavelengths has to be raised if we are to keep the deltaE from dropping to nearly nothing because the L* is so low. But we are not likely to see many such sources IRL.
Interesting... As far as "many such source", I guess it depends on whether the red and blue channels of "typical" RGB LEDs would be in the problem wavelengths. Obviously you're going to have some serious metamerism issues in your scene, but an idea of where a camera is going to start having serious issues with the scene lighting due to it causing problems later in the math pipeline would be interesting, and whether or not CFA tuning or tweaking the training set could potentially mitigate that. I need to look up where typical "consumer" blue LEDs typically lie on the spectral locus (as opposed to the extreme case of something like a royal blue/dental Luxeon...)
If red and blue LEDs typically found in RGB LED fixtures doe lie in the "problem" wavelengths, then - I've seen such sources frequently. A local concert venue owner LOVED RGB LED lighting and his favorite color was purple... Some of this (and your work prompting me to reread some of Anders' documentation including his comments on loss of tonality) might explain why I've often had some really strange results trying to handle those scenes and how to revisit them.