Actually it's not the temperature swings that would have a negative impact, it's the Heat. Heat is what kills Li-ion batteries, and that final 10% of the charging cycle is what builds up the most heat (as does baking it in a car).
R2
Why would the last 10% create the most heat? During this the current is reducing towards zero.
Probably it's accumulating more slowly but is adding to the heat already there from earlier charging, until the cooling to ambient temperature is faster than the warming from charging. This would be another reason to charge slowly instead of quickly. Heat could dissipate while charging. I have a feeling Canon have figured all those details out and taper off the charge appropriately.
Thanks Victor, I didn't have time to explain any more thoroughly (had to head to work). The heat accumulates the most by the end of the charging cycle. It's very bad to charge (or keep charging) a hot battery!
It won't be hot R2. The charge currents are small.
The current is tapered as per the expeditions of the cell manufacturer until the expected cutoff, probably around 30mA.
It is quite plausible the end of the cycle isnt the point of maximum temperature for a cell, and it would be unusual if it was. So I don't think this is the right way to view it.
Look at the last line in my post (which you ignored ;-) ). That of course describes Canon's circuitry (which prevents cooking of the battery during charging). However I've seen other 3rd party manuf that don't do so well!
In addition there are other factors that can come into play that will change the heat production curve of the charging cycle, such as immediately charging a hot freshly-depleted battery, or charging a battery when the ambient temperature is high. Every manuf I've seen recommends against doing either of these.
Discharge is even worse. The heat generated internally gets very high (due primarily to the increased internal resistance) as the battery gets depleted.
If we notionally say we will pull 25W, or 3A and power will reduce the temperature of the battery should be thought about as a delta from its start point. So assuming it will be hot I also don't think is correct.
Look at any temperature test curves done on Li-ion batteries. You'll see that huge spike at the end of the discharge cycle. Or just feel the thing with your hand!
I looked for such a curve but didn't find one. I do notice my laptop warming up when it is charging. I've not noticed it with Canon batteries, but I don't have them sitting on my lap when they're charging either.
It appears that discharge is what R2 was thinking about, but maximum rate of charge also won't be at the end of discharge.
There are a lot of thermal models used related to both the analysis of entropic charging but also being able to monitor/predict. For example in a car we implement certain cells discharging, other cells used in regen to better equalise the thermal energy within a pack. This is to improve performance rather than longevity
There is an open paper called something like thermal analysis of a fast charging method for high power lithium ion cells. That gives some description of ways in which thermal impacts to charging are taken into account when one wants to fast charge.
Ephemeris, you’re clearly very knowledgeable about, and professionally involved with, battery and charging technology. I asked a question earlier that I don’t think has been answered.
Main question: What do the three bars (3 green, 2 green, or 1 red) displayed on the battery info screen actually represent?
Sub questions : Are they an actual measure of “recharge performance”? If so, how is that being measured, and how/where is that information stored? On the battery IC or in the camera? Logic would suggest in the battery IC as it reads the same in different camera bodies. Or is it a “counter”, simply documenting the number of charge/discharge cycles? Or something else, such as state of discharge before recharging? Or measuring increased internal cell resistance as the battery ages?
Canon clearly wants us to buy a new battery when we see one red bar, yet the batteries continue working.