I would say, get the exposure right at the scene and experiment with white balance in post (as well as saturation/vibrance or picture controles).
I think you are right... but I'd go one step farther!
Shoot RAW, and bracket exposures over at least a 10 stop range. Go from 3 stops "over" whatever was chosen as the starting point, and take 10 shots with each exposed at 1 stop less.
Now, to me that brings about an insurmountable problem! I simply do not shoot sunsets and sunrises because of this! (I also don't like Aurora or fireworks for the same reason.)
The above gives you 10 raw files, from which can be produced at least 100,000 equally great looking images! Maybe a million. They are
all fabulous too. But you might as well use a random number generator to decide which configuration of the raw converter is best. Trying to decide any other way is just excessive frustration!
Seriously, each of the above exposures will look really neat with any of 10 different settings for White Balance, any of 10 different settings for contrast, any of 10 different settings for saturation, any of 10 different settings for contrast, and of 10 different amounts of sharpen, and any 10 different ways to crop the image. That may be a bit conservative at only 10 settings for each, but it does add up to a million different wonderful images
per exposure.
Shoot that three times and you either have to quit doing that, or take up processing the exposures you've already got as a life's work.
On the other hand, I do know at least a couple folks that love to shoot sunsets because it's the only way (according to them) that they are assured of getting at least one good picture today. That's hard to argue with...