But from a photography perspective, shouldn't I be using the sRGB profile (found under Display settings in System Preferences) to maintain consistency with my camera and LR's sRGB settings?
You are about to fall down the Alice in Wonderland rabbit hole
sRGB is a
Color Space, not a
Color Profile. These are two distinctly different items with distinctly different uses. Check out
this article .
For instance, if you are selecting on your camera to produce out-of-camera jpegs, you might select the color space of sRGB. Likewise, in your editing program, you might work in the sRGB color space. Or maybe not

You really need to read the linked articles.
On the other hand, you would
calibrate and profile your monitor as steps in implementing a
color managed workflow.
Profiling your monitor requires a device such as the excellent
x-rite i1Display Pro or the
ColorMunik. Check out B & H for pricing.
Pending further research, set your monitor for it's default of
Color LCD and press on. It's close enough for government work, and it's free
Google these terms and look at some of the articles. It's complex and not something that is easily explained in a web post. I also recommend Mr Rodney's site at
Digital Dog .
This stuff ain't light reading