Just picked up a Sony A6000 to replace my aging Canon 40D. I've noticed that the lowest ISO setting on both is 100. I fondly remember using Kodachrome 25 on my old Canon EOS 600. I guess it's because IQ can't be improved with lower ISOs on digital tech, but I'm not sure I understand why.
Anyone knowledgeable enough to share why that might be?
Because there is no such thing as "ISO 100" in digital cameras. It's just an arbitrary number.
Every camera maker tweeks their sensor and lens combo to get the apparent brightness of a photo to be the same as every other camera using the same "exposure triangle" parameters. So the
exposure settings on a tiny pocket cam are the same as a full frame. The total light of course is not the same, due to the tiny lens and sensor on the pocket cam, hence the noise is higher.
Film speed, on the other hand, was per area, so ASA 25 was the same speed regardless of the format used.