I'm tending to agree with Leon here - I think you were probably right on the line that center-weight uses for its calculations - where the camera was trying to weigh whether the darker areas (people) or brighter areas (background) took up more of a percentage of the center of the frame, enough to be given the primary 'weight' in calculating exposure. In your first shot, the woman is almost on center, with much bright background above her head, and also to the right, enough that the bright portions probably took up more than 65% of the center metering area, and was given the primary weight in determining exposure. In your second sample with the two people together, there is now more darker shadow area filling the center metering area, enough that it probably shifted the weighting to 40-50% bright, and 50-60% dark...and that changed the weighting enough to bring the shutter speed down more. In the one shot where the person is much more exposed, and the background almost blown out, it looks like the center-weight saw the person filling the majority of that frame, PLUS the background wasn't as bright as in the previous shots because the window with direct outside light wasn't right in the center area, and therefore the background was less bright than before AND there was better centering of the person in shadow, so the camera put all its weight on the shadow exposure.