Most (if not all) scientific astronomy sensors are cryogenically cooled. The cooling keeps the noise down. You also have to remember that astronomy exposures often run into hours not fractions of a second. So sensitivity becomes a very relative term.
The other kicker is that with hour-long exposures, film speed drops a lot through reciprocity loss. Film likes to see its photons all in a bunch. If only a couple are coming through at a time, it forgets it ever saw the first ones. So a film with ISO 100 at normal sub-second exposure times could be ISO 6 for 1 hour exposure times. CCD's, cryogenically cooled to reduce noise as noted above, remain linear for much longer times.
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Leonard Migliore