There is a bit of an art to polarizer use. Its effect is to block
polarized light, polarized light appears when light is reflected from
a shiny surface or off particles in the air, for instance. The filter
is directional in its effect, it will only block polarized light that
is polarized in a certain plane. That is why the filter can be
rotated, its position must be 90 degrees off the polarized light
plane for it to work!
For a test, find a building with a window. Shouldn't be too hard.
Stand outside the building, at a fairly steep angle to the window,
more to the side than directly in front of it. The optimum angle is
about 35 degrees off the plane of the window. The window reflection
is polarized light. The polarizer will allow you to get rid of most
of the reflection so that you can see into the building.
Point the lens at the window. Now rotate the polarizer. At a certain
position it should magically remove the reflection. The angle off the
window must be just about right for this to work! This effect means
that polarizers can be used inside museums to remove reflections off
glass cases - if there is enough light to use one.
The same principle applies to darkening the sky, most of the glare is
reflected, polarized light and can be removed with the filter so that
the sky goes dark blue. The effect is only noticeable at about ninety
degrees off the sun (ie the sun should be at your shoulder, not in
front of you or behind your back) and covers a relatively narrow band
of sky - hence polarizers are not really suitable for this use on a
wide-angle lens because the effect will be very uneven through the
frame!
Reflections are also visible off leaves and other vegetation, and off
the surface of water. Polarizers work there too, making vegetation
colours more saturated and allowing you to "see through" the water
surface. Roof-tiles and cobblestones are affected by polarizers in
the same way as vegetation, to a very surprising degree! Reflections
off metallic surfaces are not affected by the polarizer, however.
The polarizer can also be used as an ersatz neutral density filter,
it costs about two full stops of light. You do need fairly good
lighting to use it, in other words!