3D print material properties
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Entropy512 wrote:
Just a warning - be careful if you ever leave this in a hot car. PLA's upper temperature limit is pretty low, it's kind of notorious for degradation when it's warm.
IIRC it's just the opposite at cold temperatures, I think that while some plastics get brittle when it gets cold, PLA becomes EXTREMELY strong.
All true, and in freezing temps PLA can hold up better than steel (one proof being a shattered coupler in my ice maker's crusher that I replaced with a PLA part). PLA is also amazingly non-reactive with most chemicals.
It's worth noting that some PLAs can be heat treated to hold up a bit better: you bake 'em around 200F for something like 10 minutes to promote growth of internal crystaline structures. Some claim to be "dishwasher safe" after such treatment. Still, none of the low-temp extrudable filaments does well in a hot car for hours at 140F; prints don't fall apart, but they'll sag under load, etc., and are more prone to delamination. Some doped PLAs are a bit more temp resistant, for example conductive PLA (which contains carbo strands) and some of the ones with metal nanoparticles. However, they also tend to have poorer bonding between layers.
BTW, ABS isn't much better than PLA... think melted Lego blocks left on a radiator. Supposedly, polycarbonate and other higher-temp materials do better, but they have their own problems. You might think SLA resin prints would do better, but those plastics also tend to have PLA-like temp limits. Even laser-sintered metal prints don't do too well until after burning-out the binder and baking, which typically causes 25% shrinkage; basically, the binders used to coat the metal nanoparticles often aren't a lot different from PLA (although metal powder for sintering might be 70% metal, while the metal-doped PLA filament is usually less than 30% metal).
Easiest fix is to use one of the 3D fab houses that can make your part in more robust materials. Stereolithography using Accura 48HTR sounds promising: it claims a Tg (glass transition) between 195-212F. I suspect PAHT-CF Carbon Fiber Nylon filament on my Bambu X1 Carbon might be good enough; it has a Tg of 158F, while typical PLA is Tg around 140F. Best I can use in my Bambu would be polycarbonate with a Tg of 293F! However, most 3D printers can't print polycarbonate...